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2015届高考化学二轮专题复习测试卷:专题18 选修5 《有机化学基础》——有机物的结构与性质 测试卷doc

作者:高博亚洲  来源:高博赌场  时间:2019-11-15 04:15  点击:

球探足球比分直播   2015JIEGAOKAOHUAXUEERLUNZHUANTIFUXICESHIJUAN:ZHUANTI18 XUANXIU5 《YOUJIHUAXUEJICHU》——YOUJIWUDEJIEGOUYUXINGZHI CESHIJUAN.doc

  1.BENZHANBUBAOZHENGGAIYONGHUSHANGCHUANDEWENDANGWANZHENGXING,BUYULAN、BUBIDUINEIRONGERZHIJIEXIAZAICHANSHENGDEFANHUIWENTIBENZHANBUYUSHOULI。

  ZHUANTICESHIJUAN(SHIBA) 1.2012NIAN1YUE28RI,DUANJULISUDUHUABINGSHIJINSAIZAIJIANADAKAERJIALIKAIMU。WEILEQUEBAOSHIJINSAIDEGONGPINGHEGONGZHENG,FANXINGFENJIJIANCEZHONGXINJUEDINGCAIYONGXIANJINJISHUTIGAOXINGFENDEJIANCESHUIPING。MOUZHONGXINGFENJIDEJIEGOUJIANSHIWEI,XIALIEGUANYUTADESHUOFAZHENGQUEDESHI() A.GAIWUZHISHUYUFANGXIANGTING B.GAIWUZHIDEFENZISHISHIC15H22ClNO2 C.GAIWUZHIDEFENZIZHONGSUOYOUYUANZIGONGPINGMIAN D.GAIWUZHINENGFASHENGDEFANYINGLEIXINGYOUQUDAIFANYING、SHUIJIEFANYINGHEXIAOQUFANYING JIEXI:GAIWUZHIDEFENZIZHONGHANYOUCl、N、ODENGYUANSU,BUSHUYUTINGLEI,XUANXIANGACUOWU;GENJUGAIWUZHIDEJIEGOUJIANSHI,KEDEQIFENZISHIWEIC15H22ClNO2,XUANXIANGBZHENGQUE;GAIWUZHIDEFENZIZHONGYOUJIAJI(—CH3),QUEDINGLESUOYOUYUANZIBUKENENGZAITONGYIPINGMIANSHANG,XUANXIANGCCUOWU;GAIWUZHIDEFENZIZHONGDEBENHUANKEYIFASHENGQUDAIFANYING,ZHIJIKEYIFASHENGSHUIJIEFANYING,DANBUNENGFASHENGXIAOQUFANYING,XUANXIANGDCUOWU。 DAAN:B 2.BEINUOZHISHIYOUASIPILIN、PUREXITONGJINGHUAXUEFAZHIBEIDEJIEREZHENTONGKANGYANYAO,QIHECHENGFANYINGSHI(FANYINGTIAOJIANLVE)RUXIA: XIALIEXUSHUCUOWUDESHI() A.NaHCO3RONGYEKEQUBIEASIPILINHEPUREXITONG B.1 molASIPILINZUIDUOKEXIAOHAO2 mol NaOH C.CHANGWENXIABEINUOZHIZAISHUIZHONGDERONGJIEDUXIAOYUPUREXITONGDE D.SHIPUREXITONGFASHENGLEISIZHISHUIJIEFANYINGDECHANWUZHIYI JIEXI:ASIPILINHANYOUQIANGJI,KEYUNaHCO3RONGYEFANYINGCHANSHENGCO2,PUREXITONGZHONGDEFENQIANGJIBUNENGYUNaHCO3RONGYEFANYING,AXIANGZHENGQUE。ASIPILINZHONGZHISHUIJIESHENGCHENGDEFENQIANGJIHAIYAOJIXUYUNaOHFANYING,GU1 mol ASIPILINKEXIAOHAO3 mol NaOH,BXIANGCUOWU。BEINUOZHIZHONGYOULIANGGEZHIJI,JUNWEIZENGSHUIJI,GUQIRONGJIEDUJIAOXIAO,CXIANGZHENGQUE。PUREXITONGDESHUIJIECHANWUZHIYIWEI,DXIANGZHENGQUE。 DAAN:B 3.MOUCHANGJIANYOUJIWU(ZHIHANTAN、QING、YANGSANZHONGYUANSU)FENZIDEBILIMOXINGRUTUSUOSHI。QINGGENJUQIJIEGOUTEDIANPANDUANXIALIEYOUGUANSHUOFAZHONGZHENGQUEDESHI() GAIYOUJIWUDEHUAXUESHIWEIC2H4O2GAIYOUJIWUDESHUIRONGYECHENGSUANXINGQIESUANXINGBITANSUANQIANGGAIYOUJIWUZAIZIRANJIEZHONGFENBUHENGUANG A.QUANBUZHENGQUEB.ZHIYOUCUOWU C.ZHIYOUZHENGQUE D.QUANBUCUOWU JIEXI:GENJUTANYUANZI、QINGYUANZI、YANGYUANZIDECHENGJIANSHUYICIWEI4、1、2KEZHI,GAIBILIMOXINGSUOBIAOSHIDEWUZHIWEICH3COOH,QISUANXINGQIANGYUTANSUAN,ZAIZIRANJIEZHONGFENBUJIAOGUANG。 DAAN:A 4.BINGSUANNASHICHANGYONGDEFANGFUJIZHIYI,GAIWUZHIKEYIYOUBINGSUANYUSHAOJIANFANYINGZHIDE。XIAMIANYOUGUANBINGSUANHEBINGSUANNADESHUOFAZHONGBUZHENGQUEDESHI() A.BINGSUANYOUDUOZHONGTONGFENYIGOUTI B.BINGSUANYUYISUANHUWEITONGXIWU C.JIANYANYIZHONGTIANJIAJISHIBINGSUANNAHAISHILVHUANAKEYIYONGpHSHIZHI D.BINGSUANFENZIZHONGSANGETANYUANZIHELIANGGEYANGYUANZIYIDINGZAITONGYIGEPINGMIANSHANG JIEXI:BINGSUANMEIYOUSUOSUANLEITONGFENYIGOUTI,DANYOUJIASUANYIZHI、YISUANJIAZHIDENGTONGFENYIGOUTI,AZHENGQUE;BINGSUAN、YISUANDOUZHIYOUYIGEQIANGJIGUANNENGTUAN,ERQIEFENZIZUCHENGSHANGXIANGCHAYIGE“CH2”,SHUYUTONGXIWU,BZHENGQUE;BINGSUANNASHUIJIEXIANJIANXING,ERLVHUANABUSHUIJIE,GUKEYIYONGpHSHIZHIJIANYANBINGSUANNA、LVHUANASHUIRONGYEDEJIANXINGLAIJIANBIEERZHE,CZHENGQUE。BINGSUANFENZIZHONGSUOJITANYUANZI、LIANGGEYANGYUANZIJIYUSUOJIZHIJIEXIANGLIANDETANYUANZIZAIYIGEPINGMIANSHANG,DANJIAJITANYUANZIKENENGBUZAISHANGSHUSIYUANZISUOZAIDEPINGMIANZHONG,DCUO。 DAAN:D 5.XIALIESHUOFAZHENGQUEDESHI() JIEXI:XUANXIANGAZHONGYOUJIWUBUKENENGYOUSHUYUZHILEIWUZHIDETONGFENYIGOUTI;BZHONG1 molGAIYOUJIWUNENGYU2 mol NaOH FANYING;C4H8DETONGFENYIGOUTIZHONG,CH2===CHCH2CH3DEHECIGONGZHENQINGPUTUSHANGDEXISHOUFENGZUIDUOWEI4GE,CZHENGQUE;DXIANGZHONGYOUJIWUMINGCHENGYINGGAIWEI2-JIAJI-1-DINGXI。 DAAN:C 6.MOUZHIC6H12O2JINGSHUIJIEHOUDEDAOXIANGTONGTANYUANZISHUDESUOSUANHECHUN,ZAIBACHUNYANGHUADEDAOBINGTONG(),GAIZHISHI() JIEXI:BENTIYAOQIUGENJUZHIDESHUIJIECHANWU,TONGGUONIXIANGSIWEITUIDAOZHIDEJIEGOU。YINWEIZHISHUIJIEHOUDESUOSUAN、CHUNJUNHAN3GETANYUANZI,SUOSUANJIWEICH3CH2COOH,ERCHUNYANGHUADEDAOBINGTONG,SUOYICHUNYINGSHI2-BINGCHUN(),GUXIANGYINGDEZHIWEIC2H5COOCH(CH3)2。 DAAN:B 7.YOUXIALIE10ZHONGWUZHI:BENFEN,YISUAN,NIUYOU,BINGANSUAN,YISUANYIZHI,XIUSHUI,JIAQUAN,KEXINGNARONGYE,LVHUATIERONGYE,JINSHUNA。QIAN5ZHONGWUZHIZHONGYOU1ZHONGGENHOU5ZHONGWUZHIJUNNENGFANYING;HOU5ZHONGWUZHIZHONGYOU1ZHONGGENQIAN5ZHONGWUZHIJUNNENGFANYING,ZEZHEILIANGZHONGWUZHIFENBIESHI() A. B. C. D. JIEXI:BENTIDEZONGHEXINGJIAOQIANG,TASHEJIDUOZHONGWUZHIZHIJIANDEFANYING,DUIMEIYIZHONGWUZHIDEXINGZHIDOUBIXUSHULIANZHANGWO,CAINENGZHUNQUEJIEDA。JIEDASHIXUYAOLIANGLIANGDUIYING,LIRU,QIAN5ZHONGZHONGDEBENFENHEXIUSHUIFASHENGQUDAIFANYING,HEJIAQUANFASHENGSUOJUFANYING,HEKEXINGNARONGYEFASHENGZHONGHEFANYING,HELVHUATIERONGYEFASHENGXIANSEFANYING,HEJINSHUNAFASHENGZHIHUANFANYING;ERHOU5ZHONGZHONGDEKEXINGNARONGYEHEBENFEN、YISUAN、BINGANSUANFASHENGZHONGHEFANYING,NIUYOUHEYISUANYIZHIZAIKEXINGNARONGYEZHONGFASHENGSHUIJIEFANYING,SUOYICXIANGZHENGQUE。 DAAN:C 8.SHIPINXIANGJINGBOLUOZHIDESHENGCHANLUXIAN(FANYINGTIAOJIANLVEQU)RUXIA: XIALIEXUSHUCUOWUDESHI() A.BUZHOU(1)CHANWUZHONGCANLIUDEBENFENKEYONGFeCl3RONGYEJIANYAN B.BENFENHEBOLUOZHIJUNKEYUSUANXINGKMnO4RONGYEFASHENGFANYING C.BENYANGYISUANHEBOLUOZHIJUNKEYUNaOHRONGYEFASHENGFANYING D.BUZHOU(2)CHANWUZHONGCANLIUDEXIBINGCHUNKEYONGXIUSHUIJIANYAN JIEXI:BUZHOU(2)CHANWUWEIBOLUOZHI,BOLUOZHIZHONGYEHANYOUC===CSHUANGJIAN,SUOYIBUNENGYONGXIUSHUIJIANYANBUZHOU(2)CHANWUZHONGCANLIUDEXIBINGCHUN。 DAAN:D 9.XIEANMEISU(valinomycin)SHIYIZHONGZHIRONGXINGDEKANGSHENGSU,SHIYOU12GEFENZIZUCHENGDEHUANZHUANGHUAHEWU,TADEJIEGOUJIANSHIRUTUSUOSHI,YOUGUANSHUOFAZHENGQUEDESHI() A.XIEANMEISUSHIYIZHONGDANBAIZHI B.XIEANMEISUWANQUANSHUIJIEKEDEDAOSIZHONGANJISUAN C.XIEANMEISUWANQUANSHUIJIEHOUDECHANWUZHONGYOULIANGZHONGCHANWUHUWEITONGXIWU D.XIEANMEISUWANQUANSHUIJIE,QIZHONGYIZHONGCHANWUYUGANYOUQUAN()HUWEITONGFENYIGOUTI JIEXI:YOUTUKEKANCHUGAIWUZHIDEDANTISHI (c) SANZHONG,BUDOUWEIANJISUAN,A、BXIANGBUZHENGQUE;(b)HE(c)HUWEITONGXIWU,CZHENGQUE;(c)YUGANYOUQUANHUWEITONGFENYIGOUTI,DZHENGQUE。 DAAN:CD 10.MOUZHILEIYOUJIWUADEHUAXUESHIWEIC4H8O2。YIZHIA~EYOURUTUZHUANHUAGUANXI,ENENGFASHENGYINJINGFANYING,ZEADEJIEGOUKENENGYOU() A.1ZHONG B.2ZHONG C.3ZHONG D.4ZHONG JIEXI:YOUA~EDEZHUANHUAGUANXIZHI,B、D、C、EFENZIZHONGDETANYUANZISHUMUXIANGTONG,GUAWEIYISUANYIZHI,JINYOU1ZHONGJIEGOU。 DAAN:A 11.CONGGANJUPIZHONGFENLICHUYIZHONGTINGA,TASHIHECHENGXIANGLIAODEZHONGYAOYUANLIAO。1 mol AJINGCHOUYANGYANGHUAFENJIEHOUSHENGCHENG1 mol CH2OHE1 mol CH3CH(CHO)CH2CH2CH(CHO)COCH3。JINGJIANCE,ADEFENZIJIEGOUHANLIUYUANTANHUAN。YOUGUANCHOUYANGYANGHUAFENJIEFANYINGMOSHIRUXIA: (CH3)2C===CH—CH3(CH3)2C===O+CH3CHO YIZHICH2===CH—OH(XICHUNSHIJIEGOU:TANTANSHUANGJIANLIANJIEQIANGJI)BUNENGWENDINGCUNZAI。 SHIHUIDAXIALIEWENTI: (1)ADEHUAXUESHISHI__________,QIJIEGOUJIANSHISHI____________________。 (2)CH3CH(CHO)CH2CH2CH(CHO)COCH3YUZULIANGXINZHIQINGYANGHUATONGXUANZHUOYEFANYINGDEHUAXUEFANGCHENGSHISHI__________________________。 JIEXI:GENJUTIJIXINXIKEZHI1 mol TANTANSHUANGJIANFANYINGHOUSHENGCHENG2 molTANSUANSHUANGJIAN,ER“1 mol AJINGCHOUYANGYANGHUAFENJIEHOUSHENGCHENG1 mol CH2OHE1 mol CH3CH(CHO)CH2CH2CH(CHO)COCH3”, JI1 mol AFANYINGHOUSHENGCHENGLE4 molTANYANGSHUANGJIAN,GU1 mol AZHONGYOU2 molTANTANSHUANGJIAN,YOUADEFENZIJIEGOUZHONGHANLIUYUANTANHUANJICHANWUZHONGDE2GEQUANJISHIYOUTANTANSHUANGJIANFANYINGCHANSHENGDE,QIEZHEIGESHUANGJIANBIDINGZAILIUYUANHUANSHANG,ZELINGYITANTANSHUANGJIANZAIHUANWAI,RANHOUYUNYONGNIXIANGSIWEI,JIANGTANYANGSHUANGJIANDUIJIEERCHENGWEITANTANSHUANGJIAN,JIUKEYIDEDAOADEJIEGOUJIANSHI。 DAAN:(1)C10H16 (2)CH3CH(CHO)CH2CH2CH(CHO)COCH3+4Cu(OH)2CH3CH(COOH)CH2CH2CH(COOH)COCH3+2Cu2O↓+4H2O 12.YOUJIWUADEFENZISHIWEIC57H104O6,ZAILIUSUANCUNZAIXIAFASHENGRUXIAFANYING;A+3H2O3B+C。CFENZIZHONGHANYOU3GEQIANGJI(YIZHITONGYIGETANYUANZILIANJIELIANGGEQIANGJIDEYOUJIWUSHIBUWENDINGDE),XIANGDUIFENZIZHILIANGWEI92;BYUNaOHANWUZHIDELIANGZHIBI11HUNHEQIAHAOWANQUANFANYING。 (1)ADEMINGCHENGSHI__________,BDEFENZISHIWEI________,CDEJIEGOUJIANSHIWEI__________。 (2)YIZHIR1—CH===CH—R2 R1—COOH+R2—COOH,BD+E,DENGWUZHIDELIANGDED、EFENBIEYUZULIANGDENaOHRONGYEFANYINGSHI,XIAOHAODENaOHDEWUZHIDELIANGZHIBIWEI12,DDEXIANGDUIFENZIZHILIANGBIEDESHAO30,QIED、EJIEGOUZHONGJUNWUZHILIAN,ZEB、EDEJIEGOUJIANSHIFENBIEWEI________、__________(TIANXUHAO)。 (3)MOUTONGXUEDUIAZAIJIANXINGTIAOJIANXIADESHUIJIEJIQITAXINGZHIJINXINGLETUIDUAN,QIZHONGCUOWUDESHI__________(TIANXUHAO)。 a.QITATIAOJIANXIANGTONGSHI,SHUIJIESULVBIZAILIUSUANRONGYEZHONGKUAI b.YONGXIUDECCl4RONGYEKEQUEDINGASHIBUBAOHEYOUZHI c.AYOUXIANGWEI,CHANGWENXIAHENKENENGSHIGUTI JIEXI:BENTIZHENGQUEJIEDADEGUANJIANSHIQUEDINGCDEFENZISHI,FANGFAYOULIANGZHONG:YIZHONGSHILIYONG“CANJIFA”(JIANXIAMIANDEJUTIJIEDA);YIZHONGSHIXIANCAIHOUZHENGFA(JIXIANCAITASHIGANYOU,RANHOUJINXINGYANZHENG)。 (1)CFENZIZHONGHANYOU3GE—OH,ZAIJIEHETIMUXINXIZHIQIZHISHAOHAIHANYOU3GETANYUANZI,ZE92-3×17-3×12=5,GUCFENZIZHONGCHU3GE—OH、3GETANYUANZIWAIHAIYINGHANYOU5GEQINGYUANZI,YOUCIDECHUCDEFENZISHIWEIC3H8O3,CSHIGANYOU,JIEHEADEFENZISHIJIA、CGUANXIZHIASHIYOUZHI、BSHIYIYUANGAOJIZHIFANGSUAN,YOUZHILIANGSHOUHENGYUANLIYIQIUCHUBDEFENZISHIWEIC18H34O2(YOUSUAN)。 (2)BFENZIZHONGCUNZAITANTANSHUANGJIAN,ZAISUANXINGKMnO4RONGYEYANGHUAXIA,YIGETANTANSHUANGJIANBIANCHENGLIANGGE—COOH,YOUD、EXIAOHAONaOHDEWUZHIDELIANGDEGUANXIZHIDSHIYIYUANSUAN、ESHIERYUANSUAN,ZAIJIEHED、EDEXIANGDUIFENZIZHILIANGGUANXIZHID、EFENZIZHONGJUNYOU9GETANYUANZI,RANHOUGENJUD、EFENZIZHONGWUZHILIANQUEDINGD、EDEJIEGOU,ZUIHOUFANTUIBDEJIEGOU。 (3)AZAISUANXINGTIAOJIANXIADESHUIJIESHIKENIDE,ZAIJIANXINGTIAOJIANXIADESHUIJIEZESHIBUKENIDE,GUHOUZHESHUIJIESULVKUAIXIE,TANTANSHUANGJIANSHIXIUDECCl4RONGYETUNSEERBAOHEYOUZHIBUNENG;ASHUYUBUBAOHEYOUZHI,CHANGWENXIASHIYETI。 DAAN:(1)YOUSUANGANYOUZHIC18H34O2 CH2OHCHOHCH2OH (2)CH3(CH2)7CH===CH(CH2)7COOH HOOC(CH2)7COOH(3)c 13.BINGXIXIANAN(H2C===CH—CONH2)JUYOUZHONGDENGDUXING,TADUIRENTIKEZAOCHENGSHENJINGDUXINGHEYICHUANDUXING。BINGXIXIANANZHUYAOSHIYOUGAOTANSHUIHUAHEWU、DIDANBAIZHIDEZHIWUXINGSHIWUZAIJIARE(120YISHANG)PENGDIAOGUOCHENGZHONGXINGCHENG,TEBIEZAIHONGKAO、YOUZHASHIGENGYIXINGCHENG。BINGXIXIANANKEYIJINYIBUXINGCHENGZAIGONGYESHANGYOUYONGDEJUBINGXIXIANANLEIWUZHI。 QINGHUIDAXIALIEWENTI: (1)DDEJIEGOUJIANSHIWEI__________,FDEJIEGOUJIANSHIWEI__________。 (2)ZHIMINGXIALIEFANYINGLEIXING:A→B________________,C→D______________。 (3)BINGXIXIANANYOUDUOZHONGTONGFENYIGOUTI,XIECHUFENZIZHONGTONGSHIHANYOUQUANJIHETANTANSHUANGJIANDETONGFENYIGOUTI:________________________________。 (4)XIECHUHUAXUEFANGCHENGSHI:D→E:__________。2FENZICZAINONGLIUSUANZUOYONGXIAKEXINGCHENGYIGELIUYUANZHIHUAN,GAIFANYINGDEHUAXUEFANGCHENGSHIWEI__________。 JIEXI:YOUFWEIJUBINGXIXIANANKEZHIEWEI(CH2===CH—CONH2),JIEHEBWEIPUTAOTANG,CFENZIZHONGBUBAOHEDUWEI1,ZAINONGLIUSUAN、JIARETIAOJIANXIAFASHENGXIAOQUFANYING,KEZHIDWEI CH2===CH—COOH,FWEI,A→BFASHENGSHUIJIEFANYING,C→DFASHENGXIAOQUFANYING。 DAAN:(1)H2C===CH—COOH (2)SHUIJIEFANYINGXIAOQUFANYING (3)CH2===CH—NH—CHO、 CH2===C(NH2)—CHO、H2N—HC===CH—CHO (4)CH2===CH—COOH+NH3―→ CH2===CH—CONH2+H2O 14.YIYIXIWEIYUANLIAOHECHENGHUAHEWUCDELIUCHENGRUTUSUOSHI: (1)BHECZHONGHANYOUDEGUANNENGTUANMINGCHENGFENBIEWEI____________,__________。 (2)XIECHUADEJIEGOUJIANSHI:______________。 (3)DEFANYINGLEIXINGFENBIEWEI____________FANYINGHE____________FANYING。 (4)XIECHUYICHUNDETONGFENYIGOUTIDEJIEGOUJIANSHI:__________________________。 (5)XIECHUFANYINGHEDEHUAXUEFANGCHENGSHI: ________________________________________________________________________; ________________________________________________________________________。 (6)XIECHUBYUXINZHICu(OH)2XUANZHUOYEFANYINGDEHUAXUEFANGCHENGSHI:__________________________。 JIEXI:GENJUTIJIDEHECHENGLUXIANOOCCH3。(1)BDEGUANNENGTUANMINGCHENGSHIQUANJI,CDEGUANNENGTUANMINGCHENGWEIZHIJI。(2)ADEJIEGOUJIANSHIWEIClCH2CH2Cl。(3)WEIYIXIYUSHUIDEJIACHENGFANYING;WEILUDAITINGDESHUIJIEFANYING,SHUQUDAIFANYING。(4)YICHUNDETONGFENYIGOUTIWEICH3OCH3。(5)WEIYICHUNDECUIHUAYANGHUA,HUAXUEFANGCHENGSHIWEI2CH3CH2OH+O22CH3CHO+2H2O;WEIYISUANYUYIERCHUNDEZHIHUAFANYING,HUAXUEFANGCHENGSHIWEI2CH3COOH+HOCH2—CH2OHCH3COOCH2—CH2OOCCH3+2H2O。(6)BWEIYIQUAN,TAYUXINZHICu(OH)2XUANZHUOYEFANYINGDEHUAXUEFANGCHENGSHIWEICH3CHO+2Cu(OH)2CH3COOH+Cu2O↓+2H2O。 DAAN:JIANJIEXI

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